Proton Exchange Membrane Fuel Cell With Enhanced Durability Using Fluorinated Carbon As Electrocatalyst

¹ Université Clermont Auvergne, Université Blaise Pascal, Institut de Chimie de Clermont-Ferrandv, BP 10448, F-63000 CLERMONT-FERRAND, France
² CNRS, UMR 6296, ICCF, F-63171 Aubière, France
³ Univ. Grenoble Alpes, LEPMI, F-38000 Grenoble, France
⁴ CNRS, LEPMI, F-38000 Grenoble, France
⁵ MINES ParisTech, PSL Research University PERSEE - Centre procédés, énergies renouvelables et systèmes énergétiques, CS 10207 rue Claude Daunesse F-06904 Sophia Antipolis Cedex, France

Diane.Delbegue@univ-bpclermont.fr

Abstract

This study evaluates the fluorination of a carbon aerogel and its effects on the durability of the resulting electrocatalyst for Proton Exchange Membrane Fuel Cell (PEMFC). Fluorine has been introduced before or after platinum deposition. The different electrocatalysts are physico-chemically and electrochemically characterized, and the results discussed by comparison with commercial Pt/XC72 from E-Tek. The results demonstrate that the level of fluorination of the carbon aerogel can be controlled. The fluorination modifies the texture of the carbons by increasing the pore size and decreasing the specific surface area, but the textures remain appropriate for PEMFC applications. Two fluorination sites are observed, leading to both high covalent C-F bond and weakened ones, the quantity of which depends on whether the treatment is done before or after platinum deposition. The order of the different treatments is very important. The presence of platinum contributes to the fluorination mechanism, but leads to amorphous platinum rather inactive towards the Oxygen Reduction Reaction. Finally, a better durability was demonstrated for the fluorinated then platinized catalyst compared both to the same but not fluorinated catalyst and to the reference commercial material (based on the loss of the electrochemical real surface area after accelerated stress tests).