| Issue |
E3S Web Conf.
Volume 56, 2018
VII International Scientific Conference “Problems of Complex Development of Georesources” (PCDG 2018)
|
|
|---|---|---|
| Article Number | 03019 | |
| Number of page(s) | 7 | |
| Section | Problems of Complex Processing of Mineral Raw Materials and New Technologies of Mineral Processing | |
| DOI | https://doi.org/10.1051/e3sconf/20185603019 | |
| Published online | 26 September 2018 | |
Complex processing of titanium-rare metal raw material
1
Institute of Chemistry of Far East Branch of the Russian Academy of Sciences, Vladivostok, Russia
2
Far Eastern Federal University, Vladivostok, Russia
* Corresponding author: krisenko@ich.dvo.ru
The paper is devoted to investigation of the complex processing of titanium-rare metal raw materials with ammonium hydrodifluoride. It is stated that fluorination of the main components of the mineral raw materials with ammonium hydrodifluoride proceeds with formation of complex ammonium fluorometallates and simple fluorides. It is showed that in the process of aqueous leaching of the fluorinated mineral raw material niobium and tantalum completely pass into solution together with titanium, iron, and silicon fluoroammonium salts while all the rare-earth elements stay in the insoluble residue as complex fluorosodium salts together with CaF2. The method of separation of the fluoroammonium salts with obtaining marketable products and isolation of the rare-earth elements from the insoluble residue is offered.
© The Authors, published by EDP Sciences, 2018
This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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