| Issue |
E3S Web Conf.
Volume 185, 2020
2020 International Conference on Energy, Environment and Bioengineering (ICEEB 2020)
|
|
|---|---|---|
| Article Number | 04045 | |
| Number of page(s) | 6 | |
| Section | Chemical Engineering and Food Biotechnology | |
| DOI | https://doi.org/10.1051/e3sconf/202018504045 | |
| Published online | 01 September 2020 | |
Determination and Calculation of Phase Equilibrium for Aqueous Ternary System (NH2)2CO+KCl+H2O at 283.15K
1 School of Chemistry and chemical engineering, Guizhou University, Guiyang, 550025, P.R. China
2 Shaanxi Metallurgical Design & Research Institute Co., Ltd., Xi’an710016, P.R. China
* Corresponding author: jzhu1@gzu.edu.cn
The solid-liquid phase equilibrium for ternary system (NH2)2CO+KCl+H2O was determined by isothermal saturation method at 283.15K under atmosphere pressure. The isothermal phase diagrams was drawn in according to the measured solubility data. There are one co-saturated point and two pure solids occurred in this ternary system. The solid phases were confirmed by Schreinemaker’s wet residue method and X-ray powder diffraction. Two thermodynamic models, Wilson model and NRTL model, were used to calculate the solubility data. The value of root mean-square deviation in Wilson model and NRTL model for this ternary system was 0.22 and 0.66 respectively, and the value of relative average deviation was 0.61% and 2.33% respectively, which indicated that the calculated data and the experimental results are nearly consistent.
© The Authors, published by EDP Sciences, 2020
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