| Issue |
E3S Web Conf.
Volume 206, 2020
2020 2nd International Conference on Geoscience and Environmental Chemistry (ICGEC 2020)
|
|
|---|---|---|
| Article Number | 02023 | |
| Number of page(s) | 5 | |
| Section | Earth Climate Change And Environmental Chemical Pollution Control | |
| DOI | https://doi.org/10.1051/e3sconf/202020602023 | |
| Published online | 11 November 2020 | |
Preparation of high molecular weight polyvinyl alcohol by emulsifier-free emulsion polymerization
1 State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai, 201620, China
2 College of Material and Textile Engineering, Jiaxing University, Zhejiang, 314001, China
* Corresponding Address: lmzou@dhu.edu.cn
In this report, high molecular weight polyvinyl alcohol (PVA) was prepared by emulsifier-free emulsion polymerization, using the redox initiator of potassium persulfate (KPS) / N,N-dimethyl ethanolamine (DMEA). The structure and property of PVA were studied by using ubbelohde viscometer, fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance hydrogen spectroscopy (1H-NMR), X-ray Diffraction (XRD), differential scanning calorimeter (DSC) and thermo gravimetric analysis (TGA). The results showed that the viscosity-average degree of polymerization (DP) of PVA 7506, which was much higher than that of PVA commonly used in industrial production. The syndiotacticity and crystallinity of PVA was 54.2 % and 35.6 %, respectively.
© The Authors, published by EDP Sciences, 2020
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