Research progress on low-concentration methane oxidation using palladium-based catalysts

Wuhan Second Ship Design and Research Institute, Wuhan, Hubei, 430205, China

Corresponding author’s e-mail:shunli878@163.com

Abstract

There is low concentration (0.05% to 0.5%) of CH4 leakage in marine natural gas engine exhaust. It is difficult to capture and utilize low concentration CH4 because of its stable chemical structure and high ignition temperature. Catalytic oxidation is the main method to remove low concentration CH4 from tail gas. The noble metal palladium (Pd) is the best catalytic material for the complete oxidation of low concentration CH4. In this paper, the main research progress of Pd-based catalysts is reviewed for their low-temperature activity, reliability and development cost. Initially, the impact of Pd particle dimensions and valence distribution, Pd dispersion, carrier identity and strong metal-carrier interaction (SMSI) on the catalyst's methane oxidation activity was elucidated. Then, the mechanism of methane oxidation on the surface of Pdbased catalysts is summarized; In addition, the deactivation mechanisms of Pd-based catalysts, such as high temperature sintering, water poisoning and sulphur poisoning, are described in detail. In conclusion, the major hurdles encountered in achieving full oxidation of methane at low concentrations are outlined, along with the future development direction for methane oxidation catalysts. Additionally, strategies to enhance the performance of Pd-based catalysts are briefly suggested. The modified Text maintains a clear, professional, and concise style with minimal changes.