The Study of Modification of PVC-materials by Rice Husk Ash Including Activated by Cationic Surfactant and Wollastonite on Its Basis

¹ Kazan National Research Technological University, 68 Karl Marx street, Kazan, 420015, Russia
² Moscow State University of Civil Engineering, 26, Yaroslavskoye shosse, Moscow, 129337, Russia

^* Corresponding author: as.falconi@yandex.ru

Abstract

This article examines the use of waste rice processing as a promising fillers for PVC finishing materials. Due to the presence of amorphous silicon dioxide these fillers improve the performance properties of filled PVC, while lignin and cellulose in their composition accelerate biodegradation when buried in the soil. The use of these wastes allows solving the problems of “green” chemistry and closed-cycle economy and reducing the cost of finished polymer products. The paper studies the effect of ash of rice husk and synthetic wollastonite on its basis on the diffusion processes occurring during mixing of PVC and plasticizer. Activation of the RHA surface by CATAPAV significantly affects its elemental and particle size distribution and structure porosity, leading to a decrease in the porosity of the filler, reducing its particle size and narrowing the distribution of particles and pores in size. At use of silicate fillers of optimum composition growth of tensile strength, thermal stability and decrease of plasticizer migration from PVC compositions, owing to plasticizer retention in pores of these fillers is reached.