| Issue |
E3S Web Conf.
Volume 411, 2023
VI International Conference on Actual Problems of the Energy Complex and Environmental Protection (APEC-VI-2023)
|
|
|---|---|---|
| Article Number | 01037 | |
| Number of page(s) | 8 | |
| Section | Issues of the Energy Complex | |
| DOI | https://doi.org/10.1051/e3sconf/202341101037 | |
| Published online | 10 August 2023 | |
Mathematical modeling of ethylene oxidative acetylation process
1 Karshi engineering-economics institute, Karshi, Uzbekistan
2 Samarkand State University, Samarkand, Uzbekistan
* Corresponding author: bobur160189@mail.ru
In the article, the kinetic laws, kinetics, and mechanism of the oxidative acetylation reaction of ethylene in the vapor phase were studied in detail in the 0.4%Rd+4%Cu+7%CH3 COOK/YuKTs catalyst. As a result of the research, the following optimal conditions for the reaction were selected: in the middle zone of the reactor at a temperature of 165°C, a volume velocity of 2000 h-1, a pressure of 4 atm, a ratio of ethylene to acetic acid of 4:1 and an oxygen content of 7% by volume. Under these optimal conditions, the activation energies of the reactions of vinyl acetate formation and ethylene oxidation are respectively equal to: Ea(VA) = 8.17 kcal/(mol∙K) and Ea(SO2) = 19.61 kcal/(mol∙ K). It was found that the rate of oxidation of ethylene is higher than the rate of formation of vinyl acetate when the temperature exceeds 220°C. The reaction mechanism of vinylacetate formation from ethylene and acetic acid in the presence of a palladium catalyst was proposed.
© The Authors, published by EDP Sciences, 2023
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Current usage metrics show cumulative count of Article Views (full-text article views including HTML views, PDF and ePub downloads, according to the available data) and Abstracts Views on Vision4Press platform.
Data correspond to usage on the plateform after 2015. The current usage metrics is available 48-96 hours after online publication and is updated daily on week days.
Initial download of the metrics may take a while.