Determination of water-soluble elements in PM2.5, PM10, and PM2.5-10 collected in the surroundings of power plants

¹ Department of Air Protection, Silesian University of Technology, 22B Konarskiego St., 44-100 Gliwice, Poland
² Institute of Mathematics, Silesian University of Technology, 23 Kaszubska St., 44-100 Gliwice, Poland ; Konrad.Kaczmarek@polsl.pl

^* Corresponding author: elwira.zajusz-zubek@polsl.pl

Abstract

The analysis reported in this study was performed to characterize the concentrations and water-soluble content of trace elements (As, Cd, Co, Cr, Hg, Mn, Ni, Pb, Sb and Se) in PM2.5, PM10 and PM2.5-10 samples collected in the surroundings of power plants in southern Poland. The solubility of trace elements bound to PM2.5 and PM10 was higher than for PM2.5-10, and in most cases, significant differences were revealed in the relative percentage concentrations of the water-soluble fractions. The occurrence of Cd, Cr, Mn, Ni, Pb and Se in first PCA (Principal Component Analysis) factor (PC1) – indicate coal combustion processes as the potential source of these elements. Other factors indicate two further anthropogenic sources: the resuspension of road dust due to vehicular activities and waste burning in domestic sources – factor (PC2), and, soil dust sources affected by fugitive dust from the mining processes and unpaved roads, as well as transportation and deposition of coal –factor (PC3).