Partitioning and Dissolution Behavior of Metal-based Engineered Nanoparticles in Sediment and Soil Suspensions

Laboratory of Analytical Chemistry and Applied Ecochemistry, Department of Applied Analytical and Physical Chemistry, Faculty of Bioscience Engineering, Ghent University, Coupure Links 653, Ghent, BELGIUM

^a Frederik.VanKoetsem@UGent.be
^b Gijs.DuLaing@UGent.be

Abstract

Nowadays engineered nanoparticles are being used in a whole range of commercial applications and are therefore expected to inevitably find their way into the environment where their fate and behavior are still largely unknown. The objective of this study was to investigate the behavior and fate of a number of engineered nanoparticles (CeO₂, SnO₂, Ag) in sediment and soil suspensions. In particular, the association of nanoparticles with solid phases, the kinetics of these interactions, and the solubility of the nanoparticulate matter in sediment and soil suspensions were studied. Four different sediments and three different soils were sampled at various locations in Flanders (Belgium), dried, grinded and characterized. Sediment and soil suspensions were prepared with Milli-Q water (1/10 S/L), spiked with the different metallic nanoparticles or corresponding ions, and continuously shaken for 24 hours. At regular time intervals, samples of the suspensions were collected and centrifuged at 500 or 2000 rpm, or left for gravitational settling. The supernatant was analyzed for total metal contents after aqua regia digestion and for dissolved metal ions after centrifugal ultrafiltration. In a second experiment, the impact of centrifugation speed on the amount of suspended matter in the supernatant was also studied. Relations between soil or sediment properties, suspended matter and metals in the supernatant were investigated. First data already point towards a strong association of nanoparticles with suspended material. The remaining data are still being collected and will be presented at the conference.