E3S Web of Conferences
Volume 1, 2013Proceedings of the 16th International Conference on Heavy Metals in the Environment
|Number of page(s)||4|
|Section||Heavy Metals in the Atmosphere III: Local Scales/Modelling|
|Published online||23 April 2013|
Analysis of trace elements in airborne particulate matters collected in Ankara, Turkey by TXRF
1 Department of Chemistry, Hacettepe University, Ankara, TURKEY
2 Department of Chemistry, University of Hamburg, Hamburg, GERMANY
The main focus point of the presented study was the assessment of atmospheric burden of particulate matter and toxic trace metals in the atmosphere of Ankara, Turkey. For this purpose, outdoor samplings were accomplished in the capital city, Ankara. The types of filters, sample collection and sample preparation methods were investigated and optimized. Analyses were provided by the total reflection X-ray fluorescence (TXRF) spectroscopic technique in Germany. Spatial and temporal variations of air particulate matter (APM) levels in the city were examined. In some stations, APM sampled in according to their size distribution such as PM10 and PM2.5. Elemental characterization of size distributed PM were achieved and evaluated. It was detected that the elements mainly originated from soil in Beytepe station, from soil and solid fuel usage in Kayas station and from traffic and a variety of human activities in Sıhhiye station in air samplings. While the elements of natural origin observed in PM10 fraction, the elements from traffic and human activities were in PM2.5. Eventually, enrichment calculations were performed in order to identify the pollution sources.
Key words: Air particulate matters / spectrometric method / TXRF / air pollution / PM10 / PM2.5
© Owned by the authors, published by EDP Sciences, 2013
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 2.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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