Qualitative and chemical characteristics of mineral matter in the selected lignite deposits in light of their suitability for clean coal technologies

AGH University of Science and Technology, Poland, Faculty of Geology, Geophysics and Environmental Protection, Al. Mick iewicza 30, 30-059 Kraków

^a Corresponding author: bbiel@agh.edu.pl

Abstract

An analysis of the variability of ash content and chemical composition of coal ash is crucial when assessing the possibility of using this raw material in clean coal technologies (CCS). The paper focuses on chemical, technological and quality characteristics of ash from the combustion of lignite from Polish deposits. Ash content on a dry ash-free basis for the samples from 9 deposits varies from 1 to 50%. The most commonly observed ash content in the studied samples of lignite is in the range between 10–20%. The measured ash melting temperatures from the collected lignite samples have shown that the sintering, softening, melting and flow temperatures, determined in an oxidizing atmosphere (air), are higher than those determined in a reducing atmosphere. In the majority of Polish lignite deposits, the dominant component of ash was SiO₂, followed by CaO. When evaluating the suitability of coal in energy production, with particular emphasis on the combustion and gasification processes, it is also necessary to study the behavior of ash at high temperatures and the impact of ash on the gasification and combustion facilities. Ash fouling and slagging processes, which are heavily dependent on the ash content, composition, melting point and the content of chlorine, phosphorus and sulfur in coal, have a negative effect on the combustion process.