E3S Web Conf.
Volume 22, 2017International Conference on Advances in Energy Systems and Environmental Engineering (ASEE17)
|Number of page(s)||8|
|Published online||07 November 2017|
Selected heavy metals speciation in chemically stabilised sewage sludge
Częstochowa University of Technology, Department of Chemistry, Water and Wastewater Technology, ul. Dąbrowskiego 69, 42-200 Częstochowa, Poland
* Corresponding author: email@example.com
Selected heavy metals (Pb, Ni, Cd) were analysed in soil, digested sewage sludge as well as in the sludge stabilised with CaO or Fenton’s reagent. The dose of Fenton's reagent was as follows: Fe2+ = 1g.L-1, Fe2+/H2O2=1:100; stabilisation lasted for 2 h. Dose of CaO was equal to 1 g CaO.g d.m.-1 Total concentration of all metals in the digested sewage sludge was higher than in the soil. Chemical stabilisation of sludge with Fenton's reagent increased total metal content in the sludge as a result of total solids removal. Opposite effect was stated when the sludge was mixed with CaO. Also chemical fractions of heavy metals were identified (exchangeable, carbonate bound, iron oxides bound, organic and residual). The results indicate that stabilisation of the sludge with Fenton's reagent increased mobility of heavy metals compared to the digested sludge. Amendment of CaO increased percent share of examined metals in residual fraction, thus immobilised them and decreased their bioavailability.
© The Authors, published by EDP Sciences, 2017
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