E3S Web Conf.
Volume 38, 20182018 4th International Conference on Energy Materials and Environment Engineering (ICEMEE 2018)
|Number of page(s)||5|
|Section||Material Science and Technology|
|Published online||04 June 2018|
Enhanced photocatalytic activity of wool-ball-like TiO2 microspheres on carbon fabric and FTO substrates
School of materials science and engineering, Hubei University of Automotive Technology, Shiyan, 442002, P.R. China.
b College of Engineering and Applied Sciences, Nanjing Univerisy, Nanjing 210093, China.
c Institute of Materials Engineering, Nanjing University, Nantong 226019, Jiangsu, P. R. China.
* Corresponding author: email@example.com
The wool-ball-like TiO2 microspheres on carbon fabric (TiO2-CF) and FTO substrates (TiO2-FTO) have been synthesized by a facile hydrothermal method in alkali environment, using commercial TiO2 (P25) as precursors. The XRD results indicate that the as-prepared TiO2 have good crystallinity. And the SEM images show that the wool-ball-like TiO2 microspheres with a diameter of 2-3 μm are composed of TiO2 nanowires, which have a diameter of ~50 nm. The photocatalytic behavior of the wool-ball-like TiO2 microspheres, TiO2-CF and TiO2-FTO under ultraviolet light was investigated by a pseudo first-order kinetic model, using methyl orange (MO) as pollutant. The wool-ball-like TiO2 microspheres obtained a degradation rate constant (Kap) of 6.91×10-3 min-1 . The Kap values of TiO2-FTO and TiO2-CF reach 13.97×10-3 min-1 and 11.80×10-3 min-1, which are 2.0 and 1.7 times higher than that of pristine wool-ball-like TiO2 microspheres due to the “sum effect” between TiO2 and substrates. This study offers a facile hydrothermal method to prepare wool-ball-like TiO2 microspheres on CF and FTO substrates, which will improve the recyclability of phtocatalysts and can be extended to other fields.
© The Authors, published by EDP Sciences, 2018.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (http://creativecommons.org/licenses/by/4.0/).
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