Issue |
E3S Web Conf.
Volume 114, 2019
International Conference of Young Scientists “Energy Systems Research 2019”
|
|
---|---|---|
Article Number | 07007 | |
Number of page(s) | 4 | |
Section | Thermodynamics | |
DOI | https://doi.org/10.1051/e3sconf/201911407007 | |
Published online | 04 September 2019 |
Development of method for determination of the kinetics constants of coal char gasification in pore diffusion regimes
1 Irkutsk State University, Karla Marksa st. 1, Irkutsk, Russia
2 Melentiev Energy Systems Institute SB RAS, 130 Lermontova st., Irkutsk, Russia
In this paper, we developed a method for determining the kinetic constants of partially diffusion-controlled heterogeneous reactions in a porous sample of powder. Studies have been conducted on the experimental data of thermogravimetric analysis of carbon conversion in a stream of CO2, using a new method of processing kinetic curves, to obtain updated values of the kinetic constants under conditions where widely used models are inappropriate. Data obtained can be used for a reliable assessment of the characteristics of the gasification process.
© The Authors, published by EDP Sciences, 2019
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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