E3S Web Conf.
Volume 211, 2020The 1st JESSD Symposium: International Symposium of Earth, Energy, Environmental Science and Sustainable Development 2020
|Number of page(s)||8|
|Published online||25 November 2020|
Study of carbon dioxide electrochemical reduction in flow cell system using copper modified boron-doped diamond
Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Indonesia, Depok, 16424, Indonesia
2 Nanotechnology Engineering, School of Advanced Technology and Multidisciplinary, Universitas Airlangga, Surabaya, 60115, Indonesia
3 Department of Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Yokohama, 223-8522, Japan
* Corresponding author: email@example.com
High concentrations of CO2 in the atmosphere may cause climate and environmental changes. Therefore, various research has been extensively performed to reduce CO2 by converting CO2 directly into hydrocarbons. In this research, CO2 electrochemical reduction was studied using boron-doped diamond (BDD) modified with copper nanoparticles to improve BDD electrodes’ catalytic properties. The deposition was performed by chronoamperometry technique at a potential of -0.6 V (vs. Ag/AgCl) and characterized using SEM, EDS, XPS, and cyclic voltammetry (CV). CO2 electrochemical reduction on BDD and Cu-BDD was carried out at -1.5 V (vs. Ag/AgCl) for 60 minutes. The products were analyzed using HPLC and GC. The product was mainly formic acid with a concentration of 11.33 mg/L and 33% faradaic efficiency on a Cu-BDD electrode.
© The Authors, published by EDP Sciences, 2020
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