Ways of the lead-bearing slag waste utilization

¹ М.Auezov South Kazakhstan University, Shymkent, Republic of Kazakhstan
² Almaty Technological University, Almaty, Republic of Kazakhstan

^* Corresponding author: sunrise_kz@mail.ru

Abstract

The article presents the results of research on the influence of lead production slag on the environment and ecology of the city. Due to the open storage of slags, an excess of maximum permissible levels (MPL) of lead was established: near the plant, the concentration of lead in the soil exceeds 3000 mg/kg, while the MPL is 3.2 mg/kg. The data of analyzes obtained by methods of scanning electron microscopy and X-ray microanalysis, performed on a scanning electron microscope (SEM), as well as the results of X-ray fluorescence semi-quantitative analysis, performed on an X-ray fluorescence wave-dispersive spectrometer, have been presented. The results of thermal analysis of samples in air in the 20-1000 °C temperature range are presented.It was revealed that lead slag contains a fairly high amount of toxic metal compounds. It has been established that the average content of toxic metals in slags formed as a result of the activity of a lead plant is: lead - 2, 38%; zinc - 9.81%; copper - 0.97%; iron - 25.31%; silicon oxide - 24.62%; calcium oxide - 16.21%; potassium oxide - 1.42%; sulfur - 1.35% of the total sample weight.The offered technology of a selective method for the extraction of non-ferrous metals allows to enhance the ecological state of the environment and reduce their negative impact on human health by means of the disposal of the lead production slags.