Ammonia as hydrogen carrier for transport application

¹ DIME, University of Genoa, 16145 Genova, Italy
² DICCA, University of Genoa. 16145 Genova, Italy

^* Corresponding author: massimo.rivarolo@unige.it

Abstract

As the interest in hydrogen to help the decarbonization of the transport sector is growing fast, the interest in new methods for its storage is a key point to improve its diffusion in many contexts, investigating innovative methods. Ammonia is a promising solution, as its hydrogen content per volume unit is higher than hydrogen stored in liquid form; furthermore, ammonia does not require cryogenic temperature nor high amounts of energy for liquefaction. In this study, two different plant layouts have been investigated, considering as a case study an ammonia-to-hydrogen conversion plant to feed a bus station composed of ten hydrogen buses (106 kg H2/day). In the end, a techno-economic analysis is performed to investigate the Levelized Cost of Hydrogen production from ammonia for the two cases and evaluate the most feasible solution. For both the plant layouts, the following results are obtained: (i) the optimal size of the main components; (ii) the global energy efficiency; (iii) the purity of H2 obtained; (iv) the H2 production cost. Finally, the size effect is investigated to evaluate the economic feasibility of the best plant solution for large-scale hydrogen refuelling stations (2000 kg H2/day), which are a more representative case for future implementations.