Bio-additives for CI engines from one-pot alcoholysis reaction of lignocellulosic biomass: an experimental activity

Anna Maria Raspolli Galletti; Gianluca Caposciutti; Gianluca Pasini; Marco Antonelli; Stefano Frigo

doi:10.1051/e3sconf/202019708005

All issues

Volume 197 (2020)

E3S Web Conf., 197 (2020) 08005

References

Open Access

Issue		E3S Web Conf. Volume 197, 2020 75^th National ATI Congress – #7 Clean Energy for all (ATI 2020)


Article Number		08005
Number of page(s)		8
Section		Environmental Sustainability and Renewable Energy Sources
DOI		https://doi.org/10.1051/e3sconf/202019708005
Published online		22 October 2020

C. Antonetti, D. Licursi, S. Frigo, M. Antonelli, M. López, J.C. Parajó, A.M. Raspolli Galletti, “Complete exploitation of eucalyptus nitens: Optimization of hydrothermal conversion of its cellulose fraction to levulinic acid and butyl levulinate”, European Biomass Conference and Exhibition Proceedings2019, Pages 1329-133627th European Biomass Conference and Exhibition, EUBCE 2019; Lisbon; Portugal. [Google Scholar]
C. Antonetti, S. Gori, D. Licursi, G. Pasini, S. Frigo, M. López, J.C. Parajó, A.M. Raspolli Galletti, “One-Pot Alcoholysis of the Lignocellulosic Eucalyptus nitens Biomass to n-Butyl Levulinate, a Valuable Additive for Diesel Motor Fuel”, Catalysts 2020, 10, 509. [CrossRef] [Google Scholar]
M.M.A. Janssen, S. Pischinger, Potential of Cellulose-Derived Biofuels for Soot Free Diesel Combustion, SAE Tech. Pap. (2010) 2010-01–0335. [Google Scholar]
B.H.M. Zubel, S. Pischinger, Assessment of the Full Thermodynamic Potential of C8-Oxygenates for Clean Diesel Combustion, SAE Int. J. Fuels Lubr. (2017). [Google Scholar]
Z.H.Z. Gao, L. Zhu, X. Zou, C. Liu, B. Tian, Soot reduction effects of dibutyl ether (DBE) addition to a biodiesel surrogate in laminar coflow diffusion flames, Proc. Combust. Inst. 37 (2019) 1265–1272. [CrossRef] [Google Scholar]
S.N. Naik, V. V. Goud, P.K. Rout, A.K. Dalai, Production of first and second generation biofuels: A comprehensive review, Renew. Sustain. Energy Rev. 14 (2010) 578–597. doi:10.1016/J.RSER.2009.10.003. [CrossRef] [Google Scholar]
R.L.M.E. Christensen, A. Williams, S. Paul, S. Burton, Properties and Performance of Levulinate Esters as Diesel Blend Components, Energy Fuels. 25 (2011) 5422–5428. [CrossRef] [Google Scholar]
R.L.M.E. Christensen, J. Yanowitz, M. Ratcliff, Renewable Oxygenate Blending Effects on Gasoline Properties, Energy Fuels. 25 (2011) 4723–4733. [CrossRef] [Google Scholar]
D.C. Rakopoulos, C.D. Rakopoulos, E.G. Giakoumis, A.M. Dimaratos, D.C. Kyritsis, Effects of butanol-diesel fuel blends on the performance and emissions of a high-speed di diesel engine, Energy Convers. Manag. 51 (2010) 1989–1997. doi:10.1016/j.enconman.2010.02.032. [CrossRef] [Google Scholar]
A. Atmanli, N. Yilmaz, “A comparative analysis of n-butanol/diesel and 1-pentanol/diesel blends in a compression ignition engine”, Fuel 234 (2018), 161-169. [CrossRef] [Google Scholar]
M. Nour, Ali M.A. Attia, S. A. Nada, “Combustion, performance and emission analysis of diesel engine fuelled by higher alcohols (butanol, octanol and heptanol)/diesel blends”, Energy Conversion and Management 185 (2019), 313-329. [CrossRef] [Google Scholar]
A. O. Emiroğlu, “Effect of fuel injection pressure on the characteristics of single cylinder diesel engine powered by butanol-diesel blend”, Fuel 256 (2019), 115928. [CrossRef] [Google Scholar]
I.M. Yusri, R. Mamat, M.K. Akasyah, M.F. Jamlos, A.F. Yusop, “Evaluation of engine combustion and exhaust emissions characteristics using diesel/butanol blended fuel”, Applied Thermal Engineering 156 (2019), 209-219. [CrossRef] [Google Scholar]
K.H. Kim, B. Choi, S. Park, E. Kim, D. Chiaramonti, “Emission characteristics of compression ignition (CI) engine using diesel blended with hydrated butanol”, Fuel 257 (2019), 116037. [CrossRef] [Google Scholar]
H. Kuszewski, “Experimental study of the autoignition properties of n-butanol–diesel fuel blends at various ambient gas temperatures”, Fuel 235 (2019) 1316-1326. [CrossRef] [Google Scholar]
J. K. Mwangi, W-J. Lee, Y-C Chang, C-Y Chen, L-C Wang, “An overview: Energy saving and pollution reduction by using green fuel blends in diesel engines”, Applied Energy 159 (2015), 214-236. [CrossRef] [Google Scholar]
Soo-Young No, “Application of biobutanol in advanced CI engines – A review”, Fuel 183 (2016), 641-658. [CrossRef] [Google Scholar]
B. Rajesh Kumar, S. Saravanan, “Use of higher alcohol biofuels in diesel engines: A review”, Renewable and Sustainable Energy Reviews 60 (2016), 84-115. [CrossRef] [Google Scholar]
M. Vinod Babu, K. Madhu Murthy, G. Amba Prasad Rao, “Butanol and pentanol: The promising biofuels for CI engines – A review”, Renewable and Sustainable Energy Reviews 78 (2017), 1068-1088. [CrossRef] [Google Scholar]
Rust, H., Aron M., Canada Patent CA2227280 (A1) ― 1997-03-06. [Google Scholar]
A. Démolis, N. Essayem, F. Rataboul, “Synthesis and applications of alkyl levulinates”, ACS Sustain. Chem. Eng. 2, 1338–1352 (2014). [CrossRef] [Google Scholar]
L. Deng, C. Chang, R. An, X. Qi, G. Xu, “Metal sulfates-catalyzed butanolysis of cellulose: butyl levulinate production and optimization”, Cellulose 24, 5403–5415 (2017). [CrossRef] [Google Scholar]
P. Benito et al., “Tunable copper-hydrotalcite derived mixed oxides for sustainable ethanol condensation to nbutanol in liquid phase”, J. Clean. Prod. 209, 1614–1623 (2019). [CrossRef] [Google Scholar]
E. Koivisto, N. Ladommatos, M. Gold, The influence of various oxygenated functional groups in carbonyl and ether compounds on compression ignition and exhaust gas emissions, Fuel. 159 (2015) 697–711. [CrossRef] [Google Scholar]
A.E. Dodd, Z. Holubecki, “The measurement of Diesel exhaust smoke”, M.I.R.A report, 1965/10. [Google Scholar]
D.R. Tree, K.I. Svensson, “Soot processes in compression ignition engines”, Prog. Energy Combust Sci. 33 (2007), pag. 272–309. [CrossRef] [Google Scholar]
D.C.K. Rao, S. Karmakar, S. Basu, “Atomization characteristics and instabilities in the combustion of multicomponent fuel droplets with high volatility differential”, Sci Rep 7, 8925 (2017). [CrossRef] [PubMed] [Google Scholar]
J. C. Lasheras, A. C. Fernandez-Pello & F. L. Dryer, “Experimental Observations on the Disruptive Combustion of Free Droplets of Multicomponent Fuels”, Combustion Science and Technology, 22:5-6, 195-209, 1980. [CrossRef] [Google Scholar]

Current usage metrics show cumulative count of Article Views (full-text article views including HTML views, PDF and ePub downloads, according to the available data) and Abstracts Views on Vision4Press platform.

Data correspond to usage on the plateform after 2015. The current usage metrics is available 48-96 hours after online publication and is updated daily on week days.

Initial download of the metrics may take a while.

[1] C. Antonetti, D. Licursi, S. Frigo, M. Antonelli, M. López, J.C. Parajó, A.M. Raspolli Galletti, “Complete exploitation of eucalyptus nitens: Optimization of hydrothermal conversion of its cellulose fraction to levulinic acid and butyl levulinate”, European Biomass Conference and Exhibition Proceedings2019, Pages 1329-133627th European Biomass Conference and Exhibition, EUBCE 2019; Lisbon; Portugal. [Google Scholar]

[2] C. Antonetti, S. Gori, D. Licursi, G. Pasini, S. Frigo, M. López, J.C. Parajó, A.M. Raspolli Galletti, “One-Pot Alcoholysis of the Lignocellulosic Eucalyptus nitens Biomass to n-Butyl Levulinate, a Valuable Additive for Diesel Motor Fuel”, Catalysts 2020, 10, 509. [CrossRef] [Google Scholar]

[3] M.M.A. Janssen, S. Pischinger, Potential of Cellulose-Derived Biofuels for Soot Free Diesel Combustion, SAE Tech. Pap. (2010) 2010-01–0335. [Google Scholar]

[4] B.H.M. Zubel, S. Pischinger, Assessment of the Full Thermodynamic Potential of C8-Oxygenates for Clean Diesel Combustion, SAE Int. J. Fuels Lubr. (2017). [Google Scholar]

[5] Z.H.Z. Gao, L. Zhu, X. Zou, C. Liu, B. Tian, Soot reduction effects of dibutyl ether (DBE) addition to a biodiesel surrogate in laminar coflow diffusion flames, Proc. Combust. Inst. 37 (2019) 1265–1272. [CrossRef] [Google Scholar]

[6] S.N. Naik, V. V. Goud, P.K. Rout, A.K. Dalai, Production of first and second generation biofuels: A comprehensive review, Renew. Sustain. Energy Rev. 14 (2010) 578–597. doi:10.1016/J.RSER.2009.10.003. [CrossRef] [Google Scholar]

[7] R.L.M.E. Christensen, A. Williams, S. Paul, S. Burton, Properties and Performance of Levulinate Esters as Diesel Blend Components, Energy Fuels. 25 (2011) 5422–5428. [CrossRef] [Google Scholar]

[8] R.L.M.E. Christensen, J. Yanowitz, M. Ratcliff, Renewable Oxygenate Blending Effects on Gasoline Properties, Energy Fuels. 25 (2011) 4723–4733. [CrossRef] [Google Scholar]

[9] D.C. Rakopoulos, C.D. Rakopoulos, E.G. Giakoumis, A.M. Dimaratos, D.C. Kyritsis, Effects of butanol-diesel fuel blends on the performance and emissions of a high-speed di diesel engine, Energy Convers. Manag. 51 (2010) 1989–1997. doi:10.1016/j.enconman.2010.02.032. [CrossRef] [Google Scholar]

[10] A. Atmanli, N. Yilmaz, “A comparative analysis of n-butanol/diesel and 1-pentanol/diesel blends in a compression ignition engine”, Fuel 234 (2018), 161-169. [CrossRef] [Google Scholar]

[11] M. Nour, Ali M.A. Attia, S. A. Nada, “Combustion, performance and emission analysis of diesel engine fuelled by higher alcohols (butanol, octanol and heptanol)/diesel blends”, Energy Conversion and Management 185 (2019), 313-329. [CrossRef] [Google Scholar]

[12] A. O. Emiroğlu, “Effect of fuel injection pressure on the characteristics of single cylinder diesel engine powered by butanol-diesel blend”, Fuel 256 (2019), 115928. [CrossRef] [Google Scholar]

[13] I.M. Yusri, R. Mamat, M.K. Akasyah, M.F. Jamlos, A.F. Yusop, “Evaluation of engine combustion and exhaust emissions characteristics using diesel/butanol blended fuel”, Applied Thermal Engineering 156 (2019), 209-219. [CrossRef] [Google Scholar]

[14] K.H. Kim, B. Choi, S. Park, E. Kim, D. Chiaramonti, “Emission characteristics of compression ignition (CI) engine using diesel blended with hydrated butanol”, Fuel 257 (2019), 116037. [CrossRef] [Google Scholar]

[15] H. Kuszewski, “Experimental study of the autoignition properties of n-butanol–diesel fuel blends at various ambient gas temperatures”, Fuel 235 (2019) 1316-1326. [CrossRef] [Google Scholar]

[16] J. K. Mwangi, W-J. Lee, Y-C Chang, C-Y Chen, L-C Wang, “An overview: Energy saving and pollution reduction by using green fuel blends in diesel engines”, Applied Energy 159 (2015), 214-236. [CrossRef] [Google Scholar]

[17] Soo-Young No, “Application of biobutanol in advanced CI engines – A review”, Fuel 183 (2016), 641-658. [CrossRef] [Google Scholar]

[18] B. Rajesh Kumar, S. Saravanan, “Use of higher alcohol biofuels in diesel engines: A review”, Renewable and Sustainable Energy Reviews 60 (2016), 84-115. [CrossRef] [Google Scholar]

[19] M. Vinod Babu, K. Madhu Murthy, G. Amba Prasad Rao, “Butanol and pentanol: The promising biofuels for CI engines – A review”, Renewable and Sustainable Energy Reviews 78 (2017), 1068-1088. [CrossRef] [Google Scholar]

[20] Rust, H., Aron M., Canada Patent CA2227280 (A1) ― 1997-03-06. [Google Scholar]

[21] A. Démolis, N. Essayem, F. Rataboul, “Synthesis and applications of alkyl levulinates”, ACS Sustain. Chem. Eng. 2, 1338–1352 (2014). [CrossRef] [Google Scholar]

[22] L. Deng, C. Chang, R. An, X. Qi, G. Xu, “Metal sulfates-catalyzed butanolysis of cellulose: butyl levulinate production and optimization”, Cellulose 24, 5403–5415 (2017). [CrossRef] [Google Scholar]

[23] P. Benito et al., “Tunable copper-hydrotalcite derived mixed oxides for sustainable ethanol condensation to nbutanol in liquid phase”, J. Clean. Prod. 209, 1614–1623 (2019). [CrossRef] [Google Scholar]

[24] E. Koivisto, N. Ladommatos, M. Gold, The influence of various oxygenated functional groups in carbonyl and ether compounds on compression ignition and exhaust gas emissions, Fuel. 159 (2015) 697–711. [CrossRef] [Google Scholar]

[25] A.E. Dodd, Z. Holubecki, “The measurement of Diesel exhaust smoke”, M.I.R.A report, 1965/10. [Google Scholar]

[26] D.R. Tree, K.I. Svensson, “Soot processes in compression ignition engines”, Prog. Energy Combust Sci. 33 (2007), pag. 272–309. [CrossRef] [Google Scholar]

[27] D.C.K. Rao, S. Karmakar, S. Basu, “Atomization characteristics and instabilities in the combustion of multicomponent fuel droplets with high volatility differential”, Sci Rep 7, 8925 (2017). [CrossRef] [PubMed] [Google Scholar]

[28] J. C. Lasheras, A. C. Fernandez-Pello & F. L. Dryer, “Experimental Observations on the Disruptive Combustion of Free Droplets of Multicomponent Fuels”, Combustion Science and Technology, 22:5-6, 195-209, 1980. [CrossRef] [Google Scholar]