Experimental study on the characteristics of formation and dissociation of CO₂ hydrates in porous media

¹ Department of Civil and Environmental Engineering, University of Nebraska-Lincoln, Omaha, NE, USA
² Department of Civil Engineering, Hongik University, Seoul, Republic of Korea

^* Corresponding author: seunghee.kim@unl.edu

Abstract

Geologic carbon sequestration (GCS) has been pursued as a feasible strategy to store the large amount of CO₂ to curb its emission to the atmosphere in an effort to mitigate the greenhouse effects. CO₂ hydrate, which can form when the pressure and temperature satisfy its stability condition, can provide a self-trapping mechanism for an offshore CO₂ geologic storage. For example, direct sequestration of CO₂ in the form of hydrate crystals can be achieved in the storage aquifer under the seafloor. Besides, the formation of CO₂ hydrates in an upper layer of the CO₂ storage zone can potentially provide a secondary caprock. These applications, however, require a thorough understanding of the formation and dissociation of CO₂ hydrates in porous media, which are largely unknown yet. In this manuscript, a laboratory study on the formation and dissociation of CO₂ hydrates in two different environments, a two- (CO₂-water) or three-phase (CO₂-water in glass beads) condition, is presented. Based on the experimental results, it can be anticipated that the pressure and temperature change will be negligible when the formation of CO₂ hydrate is induced for GCS in the actual soil/rock layers. Besides, the formation of CO₂ hydrate in porous media may be faster, compared to the two-phase bulk condition that has been typically used in many laboratory studies, as solid grains help accelerate the hydrate formation by providing nucleus sites of crystals. Further elaborations on the role of solid grains would bring a clear path for the feasible application in the subsea area.