| Issue |
E3S Web Conf.
Volume 245, 2021
2021 5th International Conference on Advances in Energy, Environment and Chemical Science (AEECS 2021)
|
|
|---|---|---|
| Article Number | 03026 | |
| Number of page(s) | 7 | |
| Section | Chemical Performance Research and Chemical Industry Technology Research and Development | |
| DOI | https://doi.org/10.1051/e3sconf/202124503026 | |
| Published online | 24 March 2021 | |
Research on the thermal hazard of N-Nitrodihydroxyethyl dinitrate (DINA) under the action of diethanolamine
1 Department of Safety Engineering, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing Jiangsu 210094, China
2 Shanxi Applied Physics-Chemistry Research Institute, Xi’an 710065, China
* Corresponding author: clp319@njust.edu.cn
N-Nitrodihydroxyethyl dinitrate (DINA) is a commonly used energetic material. In this work, the effect of diethanolamine (DEA) on the thermal stability of DINA was studied. Firstly, the decomposition kinetics of DINA under the influence of DEA was analyzed by applying dynamic differential scanning calorimeter (DSC) experiments. Then, isothermal DSC tests with the “Interruption and re-scanning” method determined that the decomposition reactions of DINA containing 29% DEA consists of four continuous steps: the first step is a n-order reaction, and the last three steps are autocatalytic reactions. The kinetic parameters of the four-step reaction model were calculated by model-fitting method. Finally, the thermal risk parameter like TMRad was predicted based on the kinetic parameters, which has certain guiding significance for the process production of DINA.
© The Authors, published by EDP Sciences, 2021
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