Issue |
E3S Web Conf.
Volume 67, 2018
The 3rd International Tropical Renewable Energy Conference “Sustainable Development of Tropical Renewable Energy” (i-TREC 2018)
|
|
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Article Number | 01010 | |
Number of page(s) | 6 | |
Section | Smart Grid and Regulation | |
DOI | https://doi.org/10.1051/e3sconf/20186701010 | |
Published online | 26 November 2018 |
Affordable and sustainable new generation of solar cells: calcium titanate (CaTiO3) - based perovskite solar cells
1
Department of Chemical Engineering, Institut Teknologi Kalimantan, Balikpapan 76127, Indonesia
2
Department of Electrical Engineering, University of Brawijaya, Malang 65145, Indonesia
* Coresponding author: lusiernawati@itk.ac.id
Indonesia is located along the equator lines with the high intensity of solar radiation averaging about 4.5 kWh of electrical energy/day. This potential leads to the selfsustaining energy possibility fulfilling the electricity needs. Due to their unique electronic structures and high-cost merit over the existing commercial PV technologies, perovskite solar cells (PSCs) have emerged as the next-generation photovoltaic candidate. Their highest power efficiency can be achieved of up to 22.1% in the last 5-6 years. However, this high efficiency came from CH3NH3PbI3 materials which contain lead, a toxic material. Herein calcium titanate (CT) as a lead-free perovskite material were synthesized through sintering of calcium carbonate (CaCO3) and titanium oxide (TiO2) by the sol-gel method. CT powders were characterized by SEM, XRF, FTIR and XRD then applied it onto the mesoporous heterojunction PSCs, with a device architecture ITO/TiO2/CaTiO3/C/ITO. By manipulating the raw material stoichiometry and heating temperature in the synthesis of CaTiO3, the device shows the highest power conversion efficiency (PCE) of 2.12%, shortcircuit current density (JSC) of 0.027 mA cm-2, open circuit voltage (VOC) of 0.212 V and fill factor (FF) of 53.90%. This sample can be an alternative way to create lead-free, largescale, and low-cost perovskite solar cells.
© The Authors, published by EDP Sciences, 2018
This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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