E3S Web Conf.
Volume 98, 201916th International Symposium on Water-Rock Interaction (WRI-16) and 13th International Symposium on Applied Isotope Geochemistry (1st IAGC International Conference)
|Number of page(s)||4|
|Section||Disposal of Radioactive Waste: Geological, Hydrogeological and Geochemical Aspects|
|Published online||07 June 2019|
LFER and the Effect of Temperature on Oxyanion Adsorption by Goethite
Geosciences Institute, Johannes Gutenberg-University, 55099 Mainz, Germany
2 Institute of Surface Chemistry, National Academy of Sciences of Ukraine, 03164 Kiev, Ukraine
* Corresponding author: email@example.com
A linear relationship between the Gibbs free energy, ΔGr,H+, of the aqueous complex deprotonation reaction, and the Gibbs free energy, ΔGr,ads, of bidentate surface complexation reaction of oxyanions was derived from modelling of temperature dependent batch equilibrium adsorption experiments. As exemplified in this study, this relationship may be exploited to predict temperature-dependent adsorption behavior of oxyanions not yet known such as pertechnetate.
© The Authors, published by EDP Sciences, 2019
This is an open access article distributed under the terms of the Creative Commons Attribution License 4.0 (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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