| Issue |
E3S Web Conf.
Volume 118, 2019
2019 4th International Conference on Advances in Energy and Environment Research (ICAEER 2019)
|
|
|---|---|---|
| Article Number | 01044 | |
| Number of page(s) | 4 | |
| Section | Energy Engineering, Materials and Technology | |
| DOI | https://doi.org/10.1051/e3sconf/201911801044 | |
| Published online | 04 October 2019 | |
Imidazole-containing Cd Metal-Organic Framework with Selective Adsorption Properties
1
School of Chemical Engineering and Food Science, Zhengzhou Institute of Technology, Zhengzhou 450044, China.
2
College of Science, Henan Agricultural University, Zhengzhou, Henan 450002, China.
* Corresponding author: yulingli2013@163.com
Metal-organic framework material [Cd(tib)(dnbpdc) (H2O)]·2DMF·2H2O (1) [tib = 1, 3, 5-tris(1-imidazolyl)benzene, H2dnbpdc = 2, 2′-dinitro-4, 4′-biphenyldicarboxylic acid] was synthesized and characterized by Thermogravimetric analyses (TGA), Powder X-ray diffraction (PXRD) analyses and Bruker D8 Advance X-ray diffractometer. The results showed that 1 was a 1D chain structure to be joined together by hydrogen bonds to generate a 3D supramolecular structure. CO2 and N2 adsorption behavior of the material was studied. It is significative that 1 can selective sorption of CO2.
© The Authors, published by EDP Sciences, 2019
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