E3S Web Conf.
Volume 290, 20212021 3rd International Conference on Geoscience and Environmental Chemistry (ICGEC 2021)
|Number of page(s)||4|
|Section||Environmental Chemistry and Chemical Technology Application|
|Published online||14 July 2021|
Synthesis and Structure of the Copper Complex[Cu2L2ox(SO4)(H2O)4](H2O)4
1 College of Chemistry and Environmental Engineering, Chongqing University of Arts And Sciences, Yongchuan 402160, China.
Chongqing Key Laboratory of Environmental Materials & Remediation Technologies, Chongqing University of Arts and Sciences, Yongchuan 402160, China.
* Corresponding author’s e-mail: firstname.lastname@example.org
The reaction of N-(pyridine-2-ylmethyl)pyrazine-2-carboxamide (HL) and copper(II) sulfate leads to the formation of a new copper complex, [Cu2L2ox(SO4)(H2O)4](H2O)4(1), in which the deprotonated amide L-ligand was oxidized to a imide Lox-exposed to the air in the presence of the Cu ion. The X-ray crystal analysis reveals that it consists of two mononuclear copper unit with different coordination modes, multiple O-H…O hydrogen bonding between water molecules or water and sulfate O atom to form 3D networks. CCDC: 2088935,1.
© The Authors, published by EDP Sciences, 2021
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Current usage metrics show cumulative count of Article Views (full-text article views including HTML views, PDF and ePub downloads, according to the available data) and Abstracts Views on Vision4Press platform.
Data correspond to usage on the plateform after 2015. The current usage metrics is available 48-96 hours after online publication and is updated daily on week days.
Initial download of the metrics may take a while.