Adsorption Performance of Glyphosate on Modified Shell Powder/Ce-N-Tio₂

¹ Hunan City University, College of Municipal and Geomatics Engineering, 413000 Yiyang, China
² Shenyang Jianzhu University, College of Municipal and Environmental Engineering, 110168 Shenyang, China
³ Hunan City University, Hunan Rural Drinking Water Quality Safety Engineering Technology Research Center, 413000 Yiyang, China
⁴ Yiyang Commodity Quality Supervision and Inspection Institute, 413000 Yiyang, China

^* Corresponding author: 249713349@qq.com

Abstract

Glyphosate is a typical dissolved organic phosphorus that can cause adverse effects on plants, animals, and humans. Modified shell powder/Ce-N-TiO₂ was synthesized by high-temperature doping, and the prepared modified shell powder/Ce-N-TiO₂ was characterized and used response surface methodology to find out the optimum condition for adsorption removal rate. The zeta characterization indicates that the doping of Ce shifts the isotropic potential of the material to the right. The FT-IR and XPS characterization indicated that glyphosate was successfully adsorbed, and the two-two interactions of pH, contact time and dosing amount had a more obvious effect on adsorption by response surface analysis. The process of glyphosate adsorption by modified shell powder/Ce-N-TiO₂ was consistent with the quasi-secondary kinetic model and Langmuir model, and the maximum adsorption amount was 66.98 mg/g. The above results may be useful for the study of other systems of glyphosate wastewater treatment.