Experimental and kinetic modeling studies on oxidation of n-heptane under oxygen enrichment in a jet-stirred reactor

¹ State Key Laboratory of Engines, Tianjin University, Tianjin, 300072, China
² Center for Combustion Energy and Key Laboratory for Thermal Science and Power Engineering of MOE, Tsinghua, University, Beijing, 100084, China

^* Corresponding author: haifengliu@tju.edu.cn

Abstract

Oxygen-enriched combustion can improve thermal efficiency and reduce CO, unburned hydrocarbons and soot emissions in internal combustion engines. There are significant differences in the combustion process and pollutant emissions between oxygen-enriched and air condition. In order to develop an improved understanding of the effect of oxygen concentration on n-heptane oxidation, the jet-stirred reactor oxidation characteristics of n-heptane were experimentally tested at temperatures of 450-950 K and pressures of 1.03 atm with the residence time (τ) of 2 s, under the condition of oxygen mole fractions from 0.055 to 0.6. Meantime, the simulations were performed on CHEMKIN. Results show that, firstly, with the increase of oxygen concentration, the NTC (Negative Temperature Coefficient) effect is weakened, mainly due to the strengthening of low-temperature reaction path, which is also the reason for the improvement of ignition stability in cold-start condition of engines. Secondly, the activity of the reaction system improves with the increase of oxygen concentration. Within 500-750 K, it is due to enhancement of the low-temperature reaction path. When the temperature is higher than 750 K, the improvement is due to the enhancement of decomposition of H2O2 and addition reaction of H and O2. Thirdly, with the increase of oxygen concentration, both the generation and consumption of CO are strengthened, which leads to the tip of the diesel spray flame changing from soot area under air condition to the CO chemiluminescence.