| Issue |
E3S Web Conf.
Volume 385, 2023
2023 8th International Symposium on Energy Science and Chemical Engineering (ISESCE 2023)
|
|
|---|---|---|
| Article Number | 04004 | |
| Number of page(s) | 6 | |
| Section | Polymer Chemistry and Chemical Research Progress | |
| DOI | https://doi.org/10.1051/e3sconf/202338504004 | |
| Published online | 04 May 2023 | |
Preparation of calcium oxide by decomposition of phosphogypsum under CO and water vapor atmosphere
State Key Laboratory of Clean Energy Utilization, Institute for Thermal Power Engineering, Zhejiang University, Hangzhou 310027, China
Phosphogypsum (PG) is an industrial solid waste, and the production of CaO by CO reduction of PG can not only solve the environmental problems caused by PG, but also turn waste into treasure to generate CaO. However, the current yield of CaO production by CO reduction of PG is low. To further improve the yield of CaO, a technical method of CaO preparation by CO-H2O synergistic reduction of PG is proposed. The impacts of CO concentration, P(H2O)/P(CO) ratio and reaction temperature are examined in this work together with FactSage thermodynamic simulations in order to determine the ideal reaction conditions and reaction mechanism. It is found that the CaO yield could reach 96.78% at 1100 °C of 3% CO and P(H2O)/P(CO) of 10. The mechanism study shows that when the CO atmosphere contains H2O, the reductive decomposition of PG by CO is actually the result of the joint action of CO, H2 and CO2. Overall, this research will help to enhance a novel technological strategy for preparing CaO by decomposition of PG.
© The Authors, published by EDP Sciences, 2023
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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