Study on Polypropylene Composites with High Thermal Conductivity and Its Preparation

¹ Institute of Energy Resource, Hebei Academy of Sciences, Shijiazhuang, 050081, China
² Shi Jiazhuang Polymer Composite Technological Innovation Center, College of Chemical Engineering, Shijiazhuang University, Shijiazhuang, 050035, China
³ Hebei University of Science and Technology, Shijiazhuang, 050018, China
⁴ Hengshui ZhongYuTieXin Waterproof Technology Co., Ltd, Hengshui, 053000, China

^* Corresponding author: zhangxl_2021@hebust.edu.cn

Abstract

Polypropylene (PP) composite materials were prepared through two molding methods of injection and compression molding, taking PP, FG as the matrix and thermal conductive filler. The effects of molding methods and FG content on the thermal conductivity of composite materials were studied, and the SEM, XRD, and thermal expansion properties of the materials were further analyzed. Results showed that thermal conductivity of the composite material increases with increasing of the FG content. When the FG content was 75 wt%, the average thermal conductivity of the composite materials prepared by injection molding and compression molding is 9.88 W·m-1·K-1 and 6.03 W·m-1·K-1, respectively. The axial thermal conductivity is 16.6 W·m-1·K-1 and 1.35 W·m-1·K-1, and the radial thermal conductivity is 5.88 W·m-1·K-1 and 26.9 W·m-1·K-1, respectively. In composite materials formed by injection molding, the flaky FG is mainly oriented vertically, while in compression molding, the flaky FG is mainly oriented horizontally.