Influence of the Expandable Graphite on the Thermal properties of a Rigid Polyurethane Foam for construction

Lenar Shafigullin; Natalya Romanova; Gulnaz Shafigullina; Yulia Sokolova

doi:10.1051/e3sconf/202126301009

All issues

Volume 263 (2021)

E3S Web Conf., 263 (2021) 01009

References

Open Access

Issue		E3S Web Conf. Volume 263, 2021 XXIV International Scientific Conference “Construction the Formation of Living Environment” (FORM-2021)


Article Number		01009
Number of page(s)		9
Section		Modern Building Materials
DOI		https://doi.org/10.1051/e3sconf/202126301009
Published online		28 May 2021

J.H. Saunders, K.C. Frisch, Chemistry of Polyurethanes (Khimiya Publ., Moscow, 1968) [Google Scholar]
J.M Buist, Eur. Polyurethane Composites (Khimiya Publ., Moscow, 1982) [Google Scholar]
L. Shi, Z.-M. Li, M.-B. Yang, B. Yin; Q.-M. Zhou, C.-R. Tian, J.-H. Wang Expandable Graphite for Halogen-Free Flame-Retardant of High-Density Rigid Polyurethane Foams, J. Polym. Plast. Technol. Eng., 44, 1323–1327 (2005) [Google Scholar]
Jing Jina, Quan-xiao Dongb, Zhong-jun Shua, Wan-jin Wangb, Kui Heb Flame retardant Properties of Polyurethane/expandable Praphite Composites, Procedia Engineering, 71, 304–309 (2014) [Google Scholar]
E M. Gottlieb, E R. Galimov, L.A. Zenitova and others Polyurethanes: synthesis, properties and application in mechanical engineering (Kazan publishing house UN-TA, Kazan, 2016) [Google Scholar]
D. Klempner, Polymeric Foams and foam technology (Professiya Publ., Saint Petersburg, 2009) [Google Scholar]
A.A. Zakharchenko, M.A. Vaniev, A.B. Kochnov, D.V. Shokova, K.A. Emelyanenkova, I.A. Novakov The current state of the research in the sphere of low-flammable polyurethane foams production, Izvestia of Volgrograd Technical State University, 228, 7–18 (2019) [Google Scholar]
UNECE Regulation No. 118. Uniform technical prescriptions concerning the burning behaviour and/or the capability to repel fuel or lubricant of materials used in the construction of certain categories of motor vehicles: UNECE Regulation No. 118 of April 6, 2004. Information on http://docs.cntd.ru/document/1200106694. [Google Scholar]
Federal law No 123-FZ of July 22, 2008 “Technical regulations for fire safety requirements” (as amended). Information on https://base.garant.ru/12161584/ [Google Scholar]
Yu.A. Mikhaylin, Heat, thermal and fire resistance of polymer materials (Nauchnye Osnovy I Tekhnologii Publ., Saint Petersburg, 2011) [Google Scholar]
Weiguo Yao, Dongyang Zhang, Yixin Zhang, Tao Fu, Dongbo Guan, Yanli Dou Synergistic Flame Retardant Effects of Expandable Graphite and Ammonium Polyphosphate in Water-Blow Polyurethane Foam, Advances in Materials Science and Engineering, Volume 2019, Article ID 6921474, 8 page https://doi.org/10.1155/2019/692147 [Google Scholar]
Ting-Ting Li, Mengfan Xing, Hongyang Wang, Shih-Yu Huang, Chengeng Fu, Ching-Wen Lou, Jia-Horng Lin Nitrogen/phosphorus synergistic flame retardantfilled flexible polyurethane foams: microstructure, compressive stress, sound absorption, and combustion resistance, RSC Adv., 9, 21192–21201 (2019) [Google Scholar]
Wang Xi, Lijun Qian*, Zhigang Huang, Yanfang Cao, Linjie Li Continuous flame-retardant actions of two phosphate esters with expandable graphite in rigid polyurethane foams, Polymer Degradation and Stability, 130, 97–102 (2016) [Google Scholar]
Bin Zhao, Dong-Yue Liu, Wen-Jun Liang, Fei La, Jun-Sheng Wang, Ya-Qing Liu Bi-phase flame-retardant actions of water-blown rigid polyurethanefoam containing diethyl-N,N-bis(2-hydroxyethyl) phosphoramide andexpandable graphite, Journal of Analytical and Applied Pyrolysis, 124, 247–255 (2017) [Google Scholar]
Wang Xi, Lijun Qian, Yajun Chen, Jingyu Wang, Xinxin Liu Addition flame-retardant behaviors of expandable graphite and [bis(2-hydroxyethyl)amino]-methyl-phosphonic acid dimethyl ester in rigid polyurethane foams, Polymer Degradation and Stability, 122, 36–43 (2015) [Google Scholar]
Information on http://www.dow-izolan.com/ru/production/construction/sandwich-panels-for-buildings-face-finishing [Google Scholar]
Information on http://chemsystem.ru/ catalog/41 [Google Scholar]
GOST 7076-99 2000 BuIlding materials and products. Method of determination of steady-state thermal conductivity and thermal resistance (Moscow, Gosstroy Rossii Publ., GUP TsPP) [Google Scholar]
Information on https://www.netzsch-thermal-analysis.com/ru/produkty-reshenija/termogravimetricheskii-analiz/tg-209-f1-libra/ [Google Scholar]
GOST R 29127-91 (ISO 7111-87) 1991 Plastics. Thermogravity of polymers (Moscow, Standartinform Publ.) [Google Scholar]
G. Camino, S. Duquesne, R. Delobel, B. Eling, C. Lindsay, T. Roels Mechanism of Expandable Graphite Fire Retardant Action in Polyurethanes, ACS Symposium Series, 797, Volume 8, 90–109 (2001) DOI: 10.1021/bk-2001-0797.ch008 [Google Scholar]
Pablo Acuña, Zhi Li, Mercedes Santiago-Calvo, Fernando Villafañe, Miguel Ángel Rodríguez-Perez, De-Yi Wang Influence of the Characteristics of Expandable Graphite on the Morphology, Thermal Properties, Fire Behaviour and Compression Performance of a Rigid Polyurethane Foam/Polymers, 11, 168 (2019) [Google Scholar]

Current usage metrics show cumulative count of Article Views (full-text article views including HTML views, PDF and ePub downloads, according to the available data) and Abstracts Views on Vision4Press platform.

Data correspond to usage on the plateform after 2015. The current usage metrics is available 48-96 hours after online publication and is updated daily on week days.

Initial download of the metrics may take a while.

[1] J.H. Saunders, K.C. Frisch, Chemistry of Polyurethanes (Khimiya Publ., Moscow, 1968) [Google Scholar]

[2] J.M Buist, Eur. Polyurethane Composites (Khimiya Publ., Moscow, 1982) [Google Scholar]

[3] L. Shi, Z.-M. Li, M.-B. Yang, B. Yin; Q.-M. Zhou, C.-R. Tian, J.-H. Wang Expandable Graphite for Halogen-Free Flame-Retardant of High-Density Rigid Polyurethane Foams, J. Polym. Plast. Technol. Eng., 44, 1323–1327 (2005) [Google Scholar]

[4] Jing Jina, Quan-xiao Dongb, Zhong-jun Shua, Wan-jin Wangb, Kui Heb Flame retardant Properties of Polyurethane/expandable Praphite Composites, Procedia Engineering, 71, 304–309 (2014) [Google Scholar]

[5] E M. Gottlieb, E R. Galimov, L.A. Zenitova and others Polyurethanes: synthesis, properties and application in mechanical engineering (Kazan publishing house UN-TA, Kazan, 2016) [Google Scholar]

[6] D. Klempner, Polymeric Foams and foam technology (Professiya Publ., Saint Petersburg, 2009) [Google Scholar]

[7] A.A. Zakharchenko, M.A. Vaniev, A.B. Kochnov, D.V. Shokova, K.A. Emelyanenkova, I.A. Novakov The current state of the research in the sphere of low-flammable polyurethane foams production, Izvestia of Volgrograd Technical State University, 228, 7–18 (2019) [Google Scholar]

[8] UNECE Regulation No. 118. Uniform technical prescriptions concerning the burning behaviour and/or the capability to repel fuel or lubricant of materials used in the construction of certain categories of motor vehicles: UNECE Regulation No. 118 of April 6, 2004. Information on http://docs.cntd.ru/document/1200106694. [Google Scholar]

[9] Federal law No 123-FZ of July 22, 2008 “Technical regulations for fire safety requirements” (as amended). Information on https://base.garant.ru/12161584/ [Google Scholar]

[10] Yu.A. Mikhaylin, Heat, thermal and fire resistance of polymer materials (Nauchnye Osnovy I Tekhnologii Publ., Saint Petersburg, 2011) [Google Scholar]

[11] Weiguo Yao, Dongyang Zhang, Yixin Zhang, Tao Fu, Dongbo Guan, Yanli Dou Synergistic Flame Retardant Effects of Expandable Graphite and Ammonium Polyphosphate in Water-Blow Polyurethane Foam, Advances in Materials Science and Engineering, Volume 2019, Article ID 6921474, 8 page https://doi.org/10.1155/2019/692147 [Google Scholar]

[12] Ting-Ting Li, Mengfan Xing, Hongyang Wang, Shih-Yu Huang, Chengeng Fu, Ching-Wen Lou, Jia-Horng Lin Nitrogen/phosphorus synergistic flame retardantfilled flexible polyurethane foams: microstructure, compressive stress, sound absorption, and combustion resistance, RSC Adv., 9, 21192–21201 (2019) [Google Scholar]

[13] Wang Xi, Lijun Qian*, Zhigang Huang, Yanfang Cao, Linjie Li Continuous flame-retardant actions of two phosphate esters with expandable graphite in rigid polyurethane foams, Polymer Degradation and Stability, 130, 97–102 (2016) [Google Scholar]

[14] Bin Zhao, Dong-Yue Liu, Wen-Jun Liang, Fei La, Jun-Sheng Wang, Ya-Qing Liu Bi-phase flame-retardant actions of water-blown rigid polyurethanefoam containing diethyl-N,N-bis(2-hydroxyethyl) phosphoramide andexpandable graphite, Journal of Analytical and Applied Pyrolysis, 124, 247–255 (2017) [Google Scholar]

[15] Wang Xi, Lijun Qian, Yajun Chen, Jingyu Wang, Xinxin Liu Addition flame-retardant behaviors of expandable graphite and [bis(2-hydroxyethyl)amino]-methyl-phosphonic acid dimethyl ester in rigid polyurethane foams, Polymer Degradation and Stability, 122, 36–43 (2015) [Google Scholar]

[16] Information on http://www.dow-izolan.com/ru/production/construction/sandwich-panels-for-buildings-face-finishing [Google Scholar]

[17] Information on http://chemsystem.ru/ catalog/41 [Google Scholar]

[18] GOST 7076-99 2000 BuIlding materials and products. Method of determination of steady-state thermal conductivity and thermal resistance (Moscow, Gosstroy Rossii Publ., GUP TsPP) [Google Scholar]

[19] Information on https://www.netzsch-thermal-analysis.com/ru/produkty-reshenija/termogravimetricheskii-analiz/tg-209-f1-libra/ [Google Scholar]

[20] GOST R 29127-91 (ISO 7111-87) 1991 Plastics. Thermogravity of polymers (Moscow, Standartinform Publ.) [Google Scholar]

[21] G. Camino, S. Duquesne, R. Delobel, B. Eling, C. Lindsay, T. Roels Mechanism of Expandable Graphite Fire Retardant Action in Polyurethanes, ACS Symposium Series, 797, Volume 8, 90–109 (2001) DOI: 10.1021/bk-2001-0797.ch008 [Google Scholar]

[22] Pablo Acuña, Zhi Li, Mercedes Santiago-Calvo, Fernando Villafañe, Miguel Ángel Rodríguez-Perez, De-Yi Wang Influence of the Characteristics of Expandable Graphite on the Morphology, Thermal Properties, Fire Behaviour and Compression Performance of a Rigid Polyurethane Foam/Polymers, 11, 168 (2019) [Google Scholar]