Evaluation of the possibility of using the water of the Bystrytsya-Nadvirnyans'ka River in Cherniiv (Ukraine) to supply the population with drinking water

^* Faculty of Geology, Geophysics and Environmental Protection, Department of Hydrogeology and Engineering Geology, AGH University of Science and Technology, Adama Mickiewicza 30 Av., 30-059 Cracow pietrzak@agh.edu.pl; wator@agh.edu.pl; ewa.kmiecik@agh.edu.pl
^** Ivano-Frankivsk National Technical University of Oil and Gas, ul. Karpacka 15, 76019 Iwano-Frankiwsk, Ukraine omandryk@mail.ua

Abstract

The article presents the results of the research carried out in order to assess the possibility of using surface water of the Bystrytsya-Nadvirnyans'ka River in Cherniiv (western Ukraine), for the public supply of water intended for human consumption. For this purpose an existing database that contains the results of analyses of surface water samples collected in 1999, 2002, 2005, 2008, 2011 and 2014 was used. Each year, from 8 to 13 samples were collected from the Bystrytsya-Nadvirnyans'ka River in Cherniiv. Physicochemical analyses of the samples taken included the determination of pH value, temperature, TDS, alkalinity, hardness, dissolved oxygen, BOD₅, COD, suspended solids and ions: Ca²⁺, Mg²⁺, Na⁺, K⁺, Fe²⁺, NH₄⁺, Cu²⁺, Cl^-, SO₄^2-, PO₄^3-, HCO₃^-, NO₂^-, NO₃^-. These chemical analyses were verified by calculation of errors based on the ionic balance.

The results of the analyses were referred to the polish applicable requirements for surface water used for public supply of water intended for human consumption and to the regulation regarding the classification of the surface water status and environmental quality standards for priority substances. The results indicate that water of the Bystrytsya-Nadvirnyans'ka River in the area of Cherniiv was out of the class in the years 1999 and 2002 due to exceeding the limit values for category A3 for Cu²⁺. On the basis of incomplete assessment of the status of the Bystrytsya-Nadvirnyans'ka River water (due to the tests limitation to the physical and chemical components) determined that the water has a bad status because it exceeded the limits for class II for Cl^-, SO₄^2-, NO₃^- and TDS. In the samples collected in 1999 and 2002 it is also observed exceeding the maximum limit concentrations for Cu²⁺.