A cataluminescence sensor for the detection of trichloroethylene based on PEG200/ZnO nanocomposite

^a Key Laboratory of Water Pollution Control and Wastewater Resource of Anhui Province, College of Environment and Energy Engineering, Anhui Jianzhu University, Hefei 230601, PR China
^b Key Laboratory of Functional Molecular Solids, Ministry of Education, College of Chemistry and Materials Science, Anhui Normal University, Wuhu 241002, China;
^c State Key Laboratory of Synthetical Automation for Process Industries, Northeastern University, Shenyang 110819, PR China

Abstract

The content of volatile organic compounds (VOCs) in the atmosphere will endanger the health and safety of human beings which makes it very important to develop a simple and rapid method for the determination of gas pollutants. Based on this, a new type of gas sensor was proposed for the detection of trichloroethylene in air. PEG200/ZnO nanocomposite were prepared by hydrothermal method. The materials were characterized by scanning electron microscope, X-ray energy spectrum and fourier infrared spectrum. The high selectivity of the materials was verified by using the cataluminescence (CTL) intensity of 9 kinds of VOCs on the surface of the materials as a reference. The results show that trichloroethylene can produce CTL response on the surface of PEG200/ZnO nanocomposite. Temperature, air flow rate and detector concentration all have certain effects on the CTL intensity. By comparing the CTL intensity under different reaction conditions, it is found that the suitable temperature and air flow rate are 120 °C, 180 mL/min and there is a good linear relationship between the relative CTL intensity and the concentration of the detected substance (y = 28.588 x - 285.56, R=0.9593). The gas sensor has the advantage of rapid response, and trichloroethylene can produce the maximum CTL on the surface of the material within 3 ~ 5 s.