Issue |
E3S Web Conf.
Volume 334, 2022
EFC21 - European Fuel Cells and Hydrogen Piero Lunghi Conference
|
|
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Article Number | 04011 | |
Number of page(s) | 6 | |
Section | Fuel Cell Technologies | |
DOI | https://doi.org/10.1051/e3sconf/202233404011 | |
Published online | 10 January 2022 |
Degradation of Ni-YSZ and Ni-GDC fuel cells after 1000 h operation: Analysis of different overpotential contributions according to electrochemical and microstructural characterization
1 Department of Energy Conversion and Storage, Technical University of Denmark, Building 310, Fysikvej, DK-2800 Lyngby, Denmark
2 DICCA, University of Genoa, Via Opera Pia 15b, 16145 Genoa, Italy
* Corresponding author: fiammettarita.bianchi@edu.unige.it
Solid Oxide Fuel Cell (SOFC) technologies are emerging as potential power generation units with limited environmental impacts. However, the main challenges towards large scale commercial applications are high costs and low lifetime compared to currently used technologies. The present study aims at understanding degradation mechanisms in SOFCs through both experimental and modelling approaches. For this purpose, two state of the art fuel cell configurations based on Ni cermet fuel electrode (either YSZ-Yttrium Stabilised Zirconia or GDC-Gadolinium Doped Ceria), YSZ electrolyte and LSCF (Lanthanum Strontium Cobalt Ferrite oxide) air electrode were chosen. The cells were tested for 1000 hours with H2 rich mixture as fuel feed and air as oxidant. Cells were characterised at several H2/H2O ratios and temperatures with air or oxygen fed to the air electrode using different techniques. These allowed the identification of kinetic parameters to be implemented in an in-house 2D Fortran based model. The model was able to successfully simulate global cell behaviour as a function of local features, and it was validated with experimental I-V curves recorded prior and post durability operation. Moreover, post-mortem microstructure characterisation was also performed to fine-tune the model towards a more accurate prediction of the degradation influence on cell performance.
© The Authors, published by EDP Sciences, 2022
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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